Dy pʼlgʻndʻ zyyatl[00] (106) pwn dy ynʼágyʻrʼal dysʻrtyyşʼan ʼwyp dʻr tʻmʻ
Ynwwʻstʼagyyşʼanz ẕw
ryʼaqşʼanz p̄wn
Dʻhydrʼáʼasqʼárbyn[01] ʼwn
Dyqʻtʼágwlʼán[02] zwyʻr[26]
myt dy hylp pwn qʼámṗywtʻr[03]-ʼassystʻd[04] Ynprʼarʻd (Y.R.) sṗʻqtrʼásqʼáṗy (Dyyatş)
dʻrlʼngt dwrk Dʻtlʻp Ṗʼagʻl (Detlef Pagel) (gʻbwyrn ʼyn Hʻrmʼannstʻyn, Qryyaz Wwʻtzlʼar, Dyyatşlʼand)
Gysn 1992
ʼyz tyyṗt ʼwn ʼybʻrgʻzʻẕt dwrk dʻr mẖbr, ʼwn myt zyyn pryyandlʻk dʻrlwybʻnyş ʼyn dy Wwʻlt Bryyt Wwʻb gʻştʻlt ©2021... unfertiger Entwurf; unready draft;
ʼanpynyşt qʼánẕʻṗt (unfinished concept) ...
Alle rot- und grünfarbenen Wörter sind ungeprüft
All red and green colored words are unproofed
106
5 Qyẕʻr[05]
ʼYn dʻm ʼarbʻt zʻnʻn dy ʼaqsʼadyyşʼan ʼwn rʻdwqẕyʻ pwn ʼAsqʼárbyq[01] zwyʻr[26] / Dʻhydrʼáʼasqʼárbyq[01] zwyʻr[26] - Rʻdʼáqs-systʻm, wwy gwt wwy dy hydrʼálytyq sʼaṗʼanʼapʼaqyyşʼan[06] pwn Dʻhydrʼáʼasqʼárbyq[01] zwyʻr[26] (DHA) ẕw Dyqʻtʼágwlʼányq[02] zwyʻr[26] (DKG) ygzʼamʼand[07]. Myt dy hylp pwn dy ʼasʻrtyynd[08] bʼandʻ ṗʼarʼamʻtʻrs, stʼandʼart[09] ʼwn qʼalʼabryyşʼan sṗʻqtrʼa pwn dy ynprʻrʻd mʻzşʻrmʼanẕ ẕw sʼabstʼansyz myt H–O - ʼwn C=O byyndyng[13] grwṗʻs, yqsṗyryʼanst byydʻ dy mʻtʼadʼalʼadzşy p̄ʼar ynprʻrʻd sṗʻqtrʼásqʼáṗyq ʼábsʻrwwʼaẕyʻ pwn dy ryʼaqşʼanz ʼwn dy yntʻrṗrytyyşʼan ʼa yqʻrdyq ştyẕn.
ʼYn dʻm qʼántʻqst, dy ṗrʼáblʻms pwn dy qʻtʼá - ʻnʼál tʼawtʼámʻrysm zʻnʻn gʻlʻrnt ʼyn ʼasʻtylʼasʻtʼánʻ ʼwn (ysʼá-)ʼasqʼárbyq[01] ʼasʼadz[26]. Dʻrẕw ʻs pʼrqʻrt ʼyz, ʼaz dy qwwʼadrʼat wwʼárẕl wwʼalwʻs pwn dy yntʼagrʼal yqstyngşʼan qʼáwʼapyşʼant pwn dy O=C - strʻtşyng mʼádʻs, wwʼás zʻnʻn ṗrʼaṗʼárşʼanʼal ẕw dy ẕw dyyṗʼáwl mʼámʻnt ʻndʻrwngʻn[10], farendert[11] zikh[11a] farglaykhable[12] dwrk sʼabstytwtyng pwn ʼrwmyqʻ byyndyng[13] grwṗʻs. Dy dʻrşyynwng pwn dy hydrʼatyʼán pwn qʻtʼá grwṗʻs qʻn zyyn nʼkgʻgʼngʻn dwrk ynprʻrʻd sṗʻqtrʼasqʼaṗy ʼyn ʼa ṗşwt mʼalʼaqywl (bwtʼanʼal). ʼYn dy dʻhydrʼáʼasqʼárbyq[01] ʼasʼadz[26] ʼyn lyyzwng, dy yntʻrṗrytyyşʼan ʼyz nʼák ʼambygywʼas, wwyyal pwn ʻtlʻkʻ ypʻqs pwn qʻgnẕyyatyq hşṗʻh. ʼÁbʻr, qlʼár dypʻrʼansyz ryzʼaltyd ʼyn dy H–O- ʼwn O=C-strʻtşyng gʻgnt[23] ẕwwyşn qrystʼalyyn bys-DHA ʼwn dy kyydryytʼad pʼárʻm pwn DHA. Wnʼambygwʼáwsly[14], dy dʻwtʻrʼatyʼán pwn dy HO-grwṗʻs ʼyz mẕlyẖ ʼyn[15] dy bys-DHA. Tʻmṗʻrʼatwr- ʼwn pH-ʼápʻngyq şyykwţ[16] myt ʼa ʼaqtʼawwyyşʼan ʻnʻrgyʻ pwn 79.3 qdzş/mʼál zʻnʻn bʼştymt p̄ʼar dy ṗrʼáẕʻs pwn sʼaṗʼánypyqʼatyʼán pwn dy DHA. Myt dy hylp pwn ʻlʻqtrʼányş dʼatn ṗrʼasʻsyng (EDV, ʻDṖ), ʼarwyp ẕw dryya ynprʻrʻd nʼármʼal sṗʻqtrʼa, nyymly pwn DHA, DKG, ʼwn ʼyynʻr wwyyatʻr rʻdwqtʼán-ʻnlʻk mʼatʻryʻ, qʻn zyyn ʼpgʻşyydt pwn dy D2O-sʼalwşʼanz. Dy pKa - wwʻrt p̄ʼar dy sʼaṗʼánypyqʼatyʼán ṗrʼádwqt (dy DKG), bʼştymt myt dy pH-tytrʼatyʼán ʼwn ynprʼarʼát-sṗʻqtrʼásqʼáṗyʻ, qʼárʼasṗʼandz ẕw dy bʼqʼnt pKa-wwʼalwʻs p̄ʼar ʼáqsʼáqʼarbʼáqsylyq ʼasʼadz[26]. Dy pʼármyrwng pwn CO2 ʼyn ṗrʻsslyngssṗʻqtrʻn qʻn zyyn ʼatrybyʼatʼad ẕw dy dʻqʼarbʼáqsylʼatywwʻ DKG. ʼÁbʻr DKG ʼyz nʼák gʼanẕ stʼabyl ʼyn hwyk qʼansʼantryyşʼanz ʼyn lyyzwng ʼyn 37°sʻlsyws[17]. Dy DKG dyqʼamṗʼáwzyşʼan ryʼaqşʼanz zʻnʻn qwwʼalʼatyytywwly ygzʼamʼand, stʼartyng pwn DKG-lʼagʻr sʼalwşʼanz, ʼwyk ʼyn dy nyytrʼal ʼwn ʼalqʼalyyn pH-gʻgnt[23], ẖwẕ myt dy ynprʻrʻd sṗʻqtrʼasqʼaṗy nʼák myt dy sṗʻqtrʼápʼátʼámʻtry, dy plwʼárʻssʻnsʻ- ʼwn ʼwyk dy ʻlʻqtrʼán ṗʼarʼamʼagnʻtyq ʼpqlʼng (EPR, ʻPʼ ??) sṗʻqtrʼasqʼaṗy. Dy byya hwyk pH-Wwʻrt pwn wwy gʻzwnt DHA wwy DKG ywwʼalwwd, rwbyn rwyt, pʼarqʻrt ẕw lwpt ynplwʼansyz ʼanstyybʼal[24] mʼatʻryʻ qʻn zyyn pʼrbwndn myt p̄ryya rʼadyqʼal ṗrʼasʻsʼaz. ʻS ʼyz gʻwwʻn gʻpwnʻn ʼa R–O ●-rʼadʼaqʼalz yndʼaqyytyng EPR sygnʼal.
ʻS ʼyz ʼa ṗrʼáblʻmʼatyq, ʼaz rʻdwqẕyʻ ʼwn ʼaqsʼadyyşʼan zʻnʻn ynplwʼanst[18] dwrk ynstʼabylytyʻs pwn DHA ʼwn DKG. Ẕw rʻdwẕyrn ʻqwwymʼálʼar NADH-qʼansʼantryyşʼanz dy DHA ʼyn dy pyzyʼalʼadzşyqʼal pH-gʻgnt[23] wwyyal pwn dy nʼák DHA-sʼaṗʼánypyqʼatyʼán blwyz dʻrʻndyqt. Dʻr zʻlbyqʻr ʼaṗlyyz ẕw rydʼaqşʼanz dwrk H–S grwṗʻ-myt sʼabstʼansyz, p̄ʼar wwʼás ʼa qlʼár rʻʼaqẕyʻ sdr[25] ʻnlʻk ẕw dy DHA sʼaṗʼánypyqʼatyʼán ʼyz gʻpwnʻn. ʼÁbʻr ʼyn ryʼaqşʼanz dwrk H–S-grwṗʻs, ʼyz ynprʻrʻd sṗʻqtrʼásqʼáṗyqʼ(al)ly[19] dytʻqtyd[20] ʼa yntʻrmydyyt ştʼat, wwʼás dʻr pʼaqtyş[21] rʻdwqẕyʻ ʼáṗrwp pwn DHA gyyt. ʼyn dy ʼaqsʼadyyşʼan ryʼaqşʼanz zʻnʻn gʻpwnʻn qlʼár ynprʻrʻd sṗʻqtrʼásqʼáṗyq dyppʻrʻnsʻs ẕwwyşn dʻrywwʼatywwʻs, wwʼás zʻnʻn nyt twygʻwwdyq ʼádʻr twygʻwwdyq pwn C(6)–O–C(3)-syqlyzʼatyʼán[22].
5 Qyẕʻr[05]
ʼYn dʻm ʼarbʻt zʻnʻn dy ʼaqsʼadyyşʼan ʼwn rʻdwqẕyʻ pwn ʼAsqʼárbyq[01] zwyʻr[26] / Dʻhydrʼáʼasqʼárbyq[01] zwyʻr[26] - Rʻdʼáqs-systʻm, wwy gwt wwy dy hydrʼálytyq sʼaṗʼanʼapʼaqyyşʼan[06] pwn Dʻhydrʼáʼasqʼárbyq[01] zwyʻr[26] (DHA) ẕw Dyqʻtʼágwlʼányq[02] zwyʻr[26] (DKG) ygzʼamʼand[07]. Myt dy hylp pwn dy ʼasʻrtyynd[08] bʼandʻ ṗʼarʼamʻtʻrs, stʼandʼart[09] ʼwn qʼalʼabryyşʼan sṗʻqtrʼa pwn dy ynprʻrʻd mʻzşʻrmʼanẕ ẕw sʼabstʼansyz myt H–O - ʼwn C=O byyndyng[13] grwṗʻs, yqsṗyryʼanst byydʻ dy mʻtʼadʼalʼadzşy p̄ʼar ynprʻrʻd sṗʻqtrʼásqʼáṗyq ʼábsʻrwwʼaẕyʻ pwn dy ryʼaqşʼanz ʼwn dy yntʻrṗrytyyşʼan ʼa yqʻrdyq ştyẕn.
ʼYn dʻm qʼántʻqst, dy ṗrʼáblʻms pwn dy qʻtʼá - ʻnʼál tʼawtʼámʻrysm zʻnʻn gʻlʻrnt ʼyn ʼasʻtylʼasʻtʼánʻ ʼwn (ysʼá-)ʼasqʼárbyq[01] ʼasʼadz[26]. Dʻrẕw ʻs pʼrqʻrt ʼyz, ʼaz dy qwwʼadrʼat wwʼárẕl wwʼalwʻs pwn dy yntʼagrʼal yqstyngşʼan qʼáwʼapyşʼant pwn dy O=C - strʻtşyng mʼádʻs, wwʼás zʻnʻn ṗrʼaṗʼárşʼanʼal ẕw dy ẕw dyyṗʼáwl mʼámʻnt ʻndʻrwngʻn[10], farendert[11] zikh[11a] farglaykhable[12] dwrk sʼabstytwtyng pwn ʼrwmyqʻ byyndyng[13] grwṗʻs. Dy dʻrşyynwng pwn dy hydrʼatyʼán pwn qʻtʼá grwṗʻs qʻn zyyn nʼkgʻgʼngʻn dwrk ynprʻrʻd sṗʻqtrʼasqʼaṗy ʼyn ʼa ṗşwt mʼalʼaqywl (bwtʼanʼal). ʼYn dy dʻhydrʼáʼasqʼárbyq[01] ʼasʼadz[26] ʼyn lyyzwng, dy yntʻrṗrytyyşʼan ʼyz nʼák ʼambygywʼas, wwyyal pwn ʻtlʻkʻ ypʻqs pwn qʻgnẕyyatyq hşṗʻh. ʼÁbʻr, qlʼár dypʻrʼansyz ryzʼaltyd ʼyn dy H–O- ʼwn O=C-strʻtşyng gʻgnt[23] ẕwwyşn qrystʼalyyn bys-DHA ʼwn dy kyydryytʼad pʼárʻm pwn DHA. Wnʼambygwʼáwsly[14], dy dʻwtʻrʼatyʼán pwn dy HO-grwṗʻs ʼyz mẕlyẖ ʼyn[15] dy bys-DHA. Tʻmṗʻrʼatwr- ʼwn pH-ʼápʻngyq şyykwţ[16] myt ʼa ʼaqtʼawwyyşʼan ʻnʻrgyʻ pwn 79.3 qdzş/mʼál zʻnʻn bʼştymt p̄ʼar dy ṗrʼáẕʻs pwn sʼaṗʼánypyqʼatyʼán pwn dy DHA. Myt dy hylp pwn ʻlʻqtrʼányş dʼatn ṗrʼasʻsyng (EDV, ʻDṖ), ʼarwyp ẕw dryya ynprʻrʻd nʼármʼal sṗʻqtrʼa, nyymly pwn DHA, DKG, ʼwn ʼyynʻr wwyyatʻr rʻdwqtʼán-ʻnlʻk mʼatʻryʻ, qʻn zyyn ʼpgʻşyydt pwn dy D2O-sʼalwşʼanz. Dy pKa - wwʻrt p̄ʼar dy sʼaṗʼánypyqʼatyʼán ṗrʼádwqt (dy DKG), bʼştymt myt dy pH-tytrʼatyʼán ʼwn ynprʼarʼát-sṗʻqtrʼásqʼáṗyʻ, qʼárʼasṗʼandz ẕw dy bʼqʼnt pKa-wwʼalwʻs p̄ʼar ʼáqsʼáqʼarbʼáqsylyq ʼasʼadz[26]. Dy pʼármyrwng pwn CO2 ʼyn ṗrʻsslyngssṗʻqtrʻn qʻn zyyn ʼatrybyʼatʼad ẕw dy dʻqʼarbʼáqsylʼatywwʻ DKG. ʼÁbʻr DKG ʼyz nʼák gʼanẕ stʼabyl ʼyn hwyk qʼansʼantryyşʼanz ʼyn lyyzwng ʼyn 37°sʻlsyws[17]. Dy DKG dyqʼamṗʼáwzyşʼan ryʼaqşʼanz zʻnʻn qwwʼalʼatyytywwly ygzʼamʼand, stʼartyng pwn DKG-lʼagʻr sʼalwşʼanz, ʼwyk ʼyn dy nyytrʼal ʼwn ʼalqʼalyyn pH-gʻgnt[23], ẖwẕ myt dy ynprʻrʻd sṗʻqtrʼasqʼaṗy nʼák myt dy sṗʻqtrʼápʼátʼámʻtry, dy plwʼárʻssʻnsʻ- ʼwn ʼwyk dy ʻlʻqtrʼán ṗʼarʼamʼagnʻtyq ʼpqlʼng (EPR, ʻPʼ ??) sṗʻqtrʼasqʼaṗy. Dy byya hwyk pH-Wwʻrt pwn wwy gʻzwnt DHA wwy DKG ywwʼalwwd, rwbyn rwyt, pʼarqʻrt ẕw lwpt ynplwʼansyz ʼanstyybʼal[24] mʼatʻryʻ qʻn zyyn pʼrbwndn myt p̄ryya rʼadyqʼal ṗrʼasʻsʼaz. ʻS ʼyz gʻwwʻn gʻpwnʻn ʼa R–O ●-rʼadʼaqʼalz yndʼaqyytyng EPR sygnʼal.
ʻS ʼyz ʼa ṗrʼáblʻmʼatyq, ʼaz rʻdwqẕyʻ ʼwn ʼaqsʼadyyşʼan zʻnʻn ynplwʼanst[18] dwrk ynstʼabylytyʻs pwn DHA ʼwn DKG. Ẕw rʻdwẕyrn ʻqwwymʼálʼar NADH-qʼansʼantryyşʼanz dy DHA ʼyn dy pyzyʼalʼadzşyqʼal pH-gʻgnt[23] wwyyal pwn dy nʼák DHA-sʼaṗʼánypyqʼatyʼán blwyz dʻrʻndyqt. Dʻr zʻlbyqʻr ʼaṗlyyz ẕw rydʼaqşʼanz dwrk H–S grwṗʻ-myt sʼabstʼansyz, p̄ʼar wwʼás ʼa qlʼár rʻʼaqẕyʻ sdr[25] ʻnlʻk ẕw dy DHA sʼaṗʼánypyqʼatyʼán ʼyz gʻpwnʻn. ʼÁbʻr ʼyn ryʼaqşʼanz dwrk H–S-grwṗʻs, ʼyz ynprʻrʻd sṗʻqtrʼásqʼáṗyqʼ(al)ly[19] dytʻqtyd[20] ʼa yntʻrmydyyt ştʼat, wwʼás dʻr pʼaqtyş[21] rʻdwqẕyʻ ʼáṗrwp pwn DHA gyyt. ʼyn dy ʼaqsʼadyyşʼan ryʼaqşʼanz zʻnʻn gʻpwnʻn qlʼár ynprʻrʻd sṗʻqtrʼásqʼáṗyq dyppʻrʻnsʻs ẕwwyşn dʻrywwʼatywwʻs, wwʼás zʻnʻn nyt twygʻwwdyq ʼádʻr twygʻwwdyq pwn C(6)–O–C(3)-syqlyzʼatyʼán[22].
| Tʼán: Nota: | Yyidyş synʼányms: Jiddische Synonyme: |
| 00) | zyyatl
blʼat |
| 01) | (Dʻhydrʼ-)áʼasqʼárbyn zwyʻr[26] (dts.Lehnwort)
(Dʻhydrʼ-)áʼasqʼárbyq ʼasʼadz[26] (eng.Lehnwort) |
| 02) | Dyqʻtʼágwlʼán zwyʻr[26] (dts.Lehnwort)
Dyqʻtʼágwlʼányq zwyʻr[26] (eng.Lehnwort) DQG (jid.Akronym) DKG (dts.Akronym) |
| 03) | qʼámṗywtʻr
qʼalqwlʼatʼár |
| 04) | ʼassystʻd (eng.Lehnwort)
yydyd (eng.Lehnwort) bʼzyrt (dts.Lehnwort) gʻştyẕt (dts.Lehnwort) |
| 05) | qyẕʻr
sʼamʻry (eng.Lehnwort) |
| 06) | hydrʼálytyq sʼaṗʼanʼapʼaqyyşʼan
ʼalqʼalyyn hydrʼálysys |
| 07) | ynwwʻstʼagyytyd
ygzʼamʼand |
| 08) | ʼasʻrtyynd
gʻpwnʻn nʼagʻgʼanʻ qʼánstʼatʻrʻt yydʻnʼapyyd bʼştymt bʼşlʼsn (Übers.fehler ??) |
| 09) | nʼármʼal
stʼandʼart |
| 10) | dyṗʼálmʼámʻnẕʻndʻrwngʻn (Übers.fehler?)
dyyṗʼáwl mʼámʻnt ʻndʻrwngʻn |
| 11) | wwʻryd (eng.Lehnwort)
pʼrʻndʻrt (dts.Lehnwort) farendert (dts.Lehnwort) |
| 11a) | zyk
zikh |
| 12) | komparabli (eng.Lehnwort)
farglaykhable (dts.Lehnwort) qʼamṗʻrʼatywwly (eng.Lehnwort) pʼarglyyaklʻk (dts.Lehnwort) farglaykhlekh (dts.Lehnwort) |
| 13) | bwnd
byyndyng |
| 14) | qlʼr
wnʼambygwʼáwsly |
| 15) | p̄ʼar
byya ʼyn |
| 16) | bʼẕywngʻn
şyykwţ |
| 17) | °sʻlsyws
°C |
| 18) | ynplwʼanst
ʼapʻqtʼad |
| 19) | sṗʻqtrʼásqʼáṗyqʼly (eng.Lehnwort, [Adv.])
sṗʻqtrʼásqʼáṗyqʼally (eng.Lehnwort, [Adv.]) |
| 20) | dytʻqtyd
ṗrʼáwwʻn gʻwwyzn nʼkgʻgʼngʻn (??) |
| 21) | pʼaqtyş
ʻmʻs |
| 22) | syqlyzʼatyʼán
ryng pʼármyrwng |
| 23) | gʻgnt
qyyt |
| 24) | nyt stʼabyl (dts.Lehnwort, [Adv.])
wnstʼabyl (dts.Lehnwort, [Adv.]) ʼanstyybʼal (eng.Lehnwort, [Adv.]) |
| 25) | sdr
ʼárdʻnwng |
| 26) | zwyʻr [Sg.] (dts.Lehnwort)
zwyʻrs [Pl.] (dts.Lehnwort + eng.Pluralendungs-s) ʼasʼad [Sg.] (eng.Lehnwort, Verwechselung mit syr. Familienname möglich) ʼasʼadz [Pl.] (eng.Lehnwort) |
| Tʻrmynʻn (keywords): | Detlef, Pagel, Giessen, 1992, Dʻtlʻp, Ṗʼagʻl, Gysn,
DHA, DKG, EPR, NADH, pH, pKa,
|
|---|