Da-eum peiji (106) chwiim hagsul nonmun-ui ilbuibnida. Nonmun-ui ileum-ibnida:
DEHIDEULO ASEUKOLEUBIN SAN-GWA DIKETO GULRON SAN-UI
BAN-EUNG-E
GYESANGI JIWON JEOG-OESEON (IR) BUNGWANGBEOB-EULO
JOSA (Dog-il-ui)
Pagel Deteulepeu-eul tonghae balpyo (Heleuman-syutain (Hermannstein), Becheulla-eo gun (Kreis Wetzlar), Dog-il chulsaeng)
Gisen (Giessen) 1992nyeon
Geugeos-eun taipeu laiteolo sseuyeojin-eossda, mich beon-yeogdoeeossda, mich jeojaui chinjeolhan heogawa hamkke uihae Woldeu waideu web-e (World Wide Web)-e, geugeos-eun jeoja-e uihae gamdog-idoeeossda ©2011.Entwurf, Plan - draft - 초고
Alle rotfarbenen Wörter sind ungeprüft
All red colo(u)red words are unproofed
106
5 Yoyag
I nonmun-eseo, aseukoleubeu-san dehideulo-aseukoleubin-san sanhwahwan-wongye-ui sanhwa-wa gamsoga eul ppunman anila geuligo dehideulo-aseukoleubin-san(DHA)-eseo diketo-gullon-san(DKG)-kkaji alkalliseong gasu bunhaega josabad-assda. H–O mich C=O gyeolhab geulub-eul pohamhaneun muljil-ui jeog-oeseon-ui cheugjeong eulobuteoui, hwag-indoeeossdeon tti maegae byeonsu-gwa pyojun-gwa bojeong seupegteuleom ui doum-eul tonghae jeog-oeseon bungwangbeob-eul tonghae ban-eung-eul gwanchal-eul-wihan bangbeoblon-gwa haeseog-eun pilsu jiwon-eul gyeongheomhaessda.
I yeongyeol-inchi, keto-enol totomeohwa hyeonsang-ui munje-neun asetil-aseton-wa (iso-)aseukoleubeusan-e-seo gongbuhage doeeossda . Gedaga, ssang-geugja sungan byeonhwa-e bilyehan, ius chaegwon geulub-ui eung-yong peulogeulaem-e uihae bigyohal su issneun byeongyeong O=C-ppeodgi jindongmodeu jeogbun heubgwang-gyesu sagaghyeong luteu gabs-i nawassda. Keto-geulub-ui suhwa jag-yong-ui hyeonsang gandan-han bunja (butil aldehideu) eseo jeog-oeseon bungwanghag hamkke chugu doel su iss-eossda. Yeonghyang-ui myeochgaeui sangho hyogwa lo inhae sollusyeon-eissneun dehideulo aseukoleubin san wa hamkke haeseog-eun yeojeonhi moho habnida. Geuleona, bunmyeong chai sujeong gat-eun bis-DHA-wa suhwasikige doeeossdeon DHA hyeongtae saieseo H–O go C=O -ui gijigae haneun jindong-ui yeong-yeog-e-seo il-eonassda. Myeonghwaghage HO geulub-ui jungsusowa sangpyoneun bis-DHA-e daehan seong-gonghaessda. DHA-ui binuhwa gwajeong-eul wihae, ondowa pH-ui gineungjeog ilgwanseong 79.3 killo jul / mol-ui hwalseonghwa eneojilo gyeoljeong haessda. D2O (mugeoun mul) sollusyeon-es-eo jeonjajeog-in deiteo cheoli(EDP)-ui doum-eulo, choedaehan-ui se jeog-oeseon pyojun seupegteuleom bunli su issseubnida. Ideul-eun DHA, DKG, geuligo daleun han redukeuton-gwa gat-eun muljil-ibnida. Binuhwaui jepum-ui (DKG), pH-jeogjeong-e uihae geuligo jeog-oeseon-ui bungwanghag-e uihae josadoeneun pKa gabs-i, ogso tanso san-ui allyeojindoen pKa gabs-e haedang habnida. Pelles-gwa hamkke seupegteuleom-ui an-e, CO2 hyeongseong-i tal-kaleubogsilhwaibnikka DKG-e dasi ikkeul-eo gal su issda. Geuleona, 37°C-e sollusyeon-eseo nop-eun jibjung-eseo, DKG-i ajigdo aju anjeong-doeda. Jeog-oeseon-ui bungwanghag-gwa deobul-eo ajigdo bungwang-gwangdo cheugjeong, hyeong-gwang-ui deogundana jeonja sangjaseongche-ui gongmyeong1) (EPR; ESR) bungwanghag-gwa deobul-eo DKG-jusig-sollusyeon-eseo yulae, ttohan junglib geuligo alkalliseong pH-ui yeong-yeog-e DKG bunhae banjag-yong-eun jiljeog-eulo josa-bad-assda. DHA-gwa DKG modu-eseo nop-eun sando(pH) gabs-eseo lubi-ppalgang muljil-i gaebalhaessseubnida. Gongjung jung yeonghyang-eulo inhae, geugeoseun bul-anjeong, mich geugeos-eun geubjinjeog-in gongjeong-gwa gwanlyeon-i -iss-eul su issseubnida. R–O ● geubjinpa-leul galikineun han EPR sinhoga balgyeondoeeossda.
Gamso-wa sanhwa-ga DHA-wa DKG-ui bul-anjeongseong-e uihae yeonghyang-eul juge doeneun geos-eun, munjeleul pohamhada. Geuleomeulo DHA-ui chuga binuhwa ttaemun-e nikotin-amideu adenin dinyukeulle-otideuui hwan-wonhyeongtae(NADH)ui gat-eun mol nongdoga saenglihag-ui pH jiyeog-eseo DHA-leul danji bul-wanjeonhage gamsohabnida. H–S geulub-e ham-yu muljil-eul tonghae gamso-eseo, dong-il yuhyohabnida. Ileohan deul-eo, DHA binuhwa-wa yusahan myeongbaeghan ban-eung sunseo-ga balgyeondoeeossseubnida. Geuleona, H–S geulub-gwa ban-eung-hayeo, DHA-ui jinjja hwan-won ban-eung-e uihae da-eum jung-gan sangtaega jeog-oeseonbungwangbeob-e uihae jeungmyeongdoebnida. C(6)-O-C(3) golileul hyeongseong_haneun bulganeung ina neunglyeog issneun pasaeng sangpum saiui sanhwa ban-eung-eseo, myeonghwag jeog-oeseonbungwangbeob_e uihan chaiga balgyeondoeeossda.
5 Yoyag
I nonmun-eseo, aseukoleubeu-san dehideulo-aseukoleubin-san sanhwahwan-wongye-ui sanhwa-wa gamsoga eul ppunman anila geuligo dehideulo-aseukoleubin-san(DHA)-eseo diketo-gullon-san(DKG)-kkaji alkalliseong gasu bunhaega josabad-assda. H–O mich C=O gyeolhab geulub-eul pohamhaneun muljil-ui jeog-oeseon-ui cheugjeong eulobuteoui, hwag-indoeeossdeon tti maegae byeonsu-gwa pyojun-gwa bojeong seupegteuleom ui doum-eul tonghae jeog-oeseon bungwangbeob-eul tonghae ban-eung-eul gwanchal-eul-wihan bangbeoblon-gwa haeseog-eun pilsu jiwon-eul gyeongheomhaessda.
I yeongyeol-inchi, keto-enol totomeohwa hyeonsang-ui munje-neun asetil-aseton-wa (iso-)aseukoleubeusan-e-seo gongbuhage doeeossda . Gedaga, ssang-geugja sungan byeonhwa-e bilyehan, ius chaegwon geulub-ui eung-yong peulogeulaem-e uihae bigyohal su issneun byeongyeong O=C-ppeodgi jindongmodeu jeogbun heubgwang-gyesu sagaghyeong luteu gabs-i nawassda. Keto-geulub-ui suhwa jag-yong-ui hyeonsang gandan-han bunja (butil aldehideu) eseo jeog-oeseon bungwanghag hamkke chugu doel su iss-eossda. Yeonghyang-ui myeochgaeui sangho hyogwa lo inhae sollusyeon-eissneun dehideulo aseukoleubin san wa hamkke haeseog-eun yeojeonhi moho habnida. Geuleona, bunmyeong chai sujeong gat-eun bis-DHA-wa suhwasikige doeeossdeon DHA hyeongtae saieseo H–O go C=O -ui gijigae haneun jindong-ui yeong-yeog-e-seo il-eonassda. Myeonghwaghage HO geulub-ui jungsusowa sangpyoneun bis-DHA-e daehan seong-gonghaessda. DHA-ui binuhwa gwajeong-eul wihae, ondowa pH-ui gineungjeog ilgwanseong 79.3 killo jul / mol-ui hwalseonghwa eneojilo gyeoljeong haessda. D2O (mugeoun mul) sollusyeon-es-eo jeonjajeog-in deiteo cheoli(EDP)-ui doum-eulo, choedaehan-ui se jeog-oeseon pyojun seupegteuleom bunli su issseubnida. Ideul-eun DHA, DKG, geuligo daleun han redukeuton-gwa gat-eun muljil-ibnida. Binuhwaui jepum-ui (DKG), pH-jeogjeong-e uihae geuligo jeog-oeseon-ui bungwanghag-e uihae josadoeneun pKa gabs-i, ogso tanso san-ui allyeojindoen pKa gabs-e haedang habnida. Pelles-gwa hamkke seupegteuleom-ui an-e, CO2 hyeongseong-i tal-kaleubogsilhwaibnikka DKG-e dasi ikkeul-eo gal su issda. Geuleona, 37°C-e sollusyeon-eseo nop-eun jibjung-eseo, DKG-i ajigdo aju anjeong-doeda. Jeog-oeseon-ui bungwanghag-gwa deobul-eo ajigdo bungwang-gwangdo cheugjeong, hyeong-gwang-ui deogundana jeonja sangjaseongche-ui gongmyeong1) (EPR; ESR) bungwanghag-gwa deobul-eo DKG-jusig-sollusyeon-eseo yulae, ttohan junglib geuligo alkalliseong pH-ui yeong-yeog-e DKG bunhae banjag-yong-eun jiljeog-eulo josa-bad-assda. DHA-gwa DKG modu-eseo nop-eun sando(pH) gabs-eseo lubi-ppalgang muljil-i gaebalhaessseubnida. Gongjung jung yeonghyang-eulo inhae, geugeoseun bul-anjeong, mich geugeos-eun geubjinjeog-in gongjeong-gwa gwanlyeon-i -iss-eul su issseubnida. R–O ● geubjinpa-leul galikineun han EPR sinhoga balgyeondoeeossda.
Gamso-wa sanhwa-ga DHA-wa DKG-ui bul-anjeongseong-e uihae yeonghyang-eul juge doeneun geos-eun, munjeleul pohamhada. Geuleomeulo DHA-ui chuga binuhwa ttaemun-e nikotin-amideu adenin dinyukeulle-otideuui hwan-wonhyeongtae(NADH)ui gat-eun mol nongdoga saenglihag-ui pH jiyeog-eseo DHA-leul danji bul-wanjeonhage gamsohabnida. H–S geulub-e ham-yu muljil-eul tonghae gamso-eseo, dong-il yuhyohabnida. Ileohan deul-eo, DHA binuhwa-wa yusahan myeongbaeghan ban-eung sunseo-ga balgyeondoeeossseubnida. Geuleona, H–S geulub-gwa ban-eung-hayeo, DHA-ui jinjja hwan-won ban-eung-e uihae da-eum jung-gan sangtaega jeog-oeseonbungwangbeob-e uihae jeungmyeongdoebnida. C(6)-O-C(3) golileul hyeongseong_haneun bulganeung ina neunglyeog issneun pasaeng sangpum saiui sanhwa ban-eung-eseo, myeonghwag jeog-oeseonbungwangbeob_e uihan chaiga balgyeondoeeossda.
| Nota: | 한국어 동의어:
Hangug-eo dong-uieo: Koreanische Synonyme: |
| 1) | 전자 상자 성체의 공명 (EPR)
jeonja sangjaseongche-ui gongmyeong (EPR) 전자스핀의 공명 (ESR) jeonjaseupin-ui gongmyeong (ESR) |