Te whārangi ka whai ake (106) he wāhanga o te tuhinga whakapae täkutatanga tuatahi.
Te taitara o te tuhinga, ko:
NGĀ TŪHURATANGA2) KI TETAHI
NGĀ TAUHOHENGA MAI I TE WAIKAWA KĀWEIKŌARO-HAUWAITATANGO6) ME DKG8)
KI TE ĀWHINA O TE WETENGA Ā-HIHINGA4) PŌKĀKĀ(=IR) Ā-ROROHIKO
(i te reo Tiamana1) )
i whakatakotoria tuhinga e Teterepa Pākera (??) (Detlef Pagel)
(I whānau mai ki
Hermannstein (Kreis Wetzlar), Tiamana1) )
Kīhena (??) (Gießen (Giessen)) 1992
Ko te whārangi i pato a (i) whakawhitia e, a (i) maka ki roto ki te tukutuku whānui ao ki te whakaaetanga o te kaituhi © 2015... unfertiger Entwurf; unready draft; tauira mangere; ...
Alle rot- und grünfarbenen Wörter sind ungeprüft
All red and green colored words are unproofed
106
5 Whakarāpopototanga
I roto i tenei mahi, i tātarihia me te ōhikitanga me whakaitinga o te pūnaha retōh o te waikawa kāweikōaro3) me te waikawa kāweikōaro-hauwaitatango6) rite te paparetanga kawakore i waikawa kāweikōaro-hauwaitatango6) (DHA) ki DKG8) (DKG). Ki te awhina o ngā tawhā ropu kitea, o ngā hihinga o paerewa me tōkarikari (kitea) i ngā inenga pōkākā i roto i ngā matū, i ngā rōpū here o te H–O me C=O, i ite i te tautoko tino me te tukanga mō te mātakitaki i te hohenga ki te hihinga pōkākā rite te tikanga.
I roto i tenei hononga, i ako ngā raruraru9) o te takanga o te taua wāhanga hāparo-rua-waiwaro rua waihā i runga i 2,4-hāparo-rua rua pēwaro10) me waikawa (iho-)kāweikōaro.
I tua atu, ka tahuri te reira i roto i, i rerekē | te uara pakiaka tapawha | o te whakarea ngaro kura | momo wiri o totoro O=C, | e te hunga rite | ki te huringa taime dipole, | ratou auhia | i roto i | te whakauru | o ngā rōpū | here tata.
Ko te āhuatanga nei | o te hydration | o ngā rōpū keto i taea | ki te e whaia | ki te hihinga pōkākā | i roto i | te muingota māmā (hāparo-tahi pūwaro).
Ki te waikawameha "dehydroascorbic" | i roto i | otinga, he rangirua te tonu | te tikanga | no te mea | o te pānga | e rave rahi | o te mana tahi .
Heoi, hua ngā rerekētanga mārama | i waenganui i | te puka | tioata hoki | o te bis-DHA, me te puka "hydrated" o te DHA | i te rohe wiri totoro | o H–O me O=C.
E kore e rangirua te, ko angitu | mō te bis-DHA | i te "deuteration" | o te rōpū OH.
Hoki | i te tukanga | o te "saponification" | o te DHA, i whakaritea (/takoto) | "coherences" mahi | o te pāmahana | me te pH | me te pūngao whakahohe | o 79,3 kJ / mol.
Ki te awhina | o te tukatuka raraunga hiko (TRH), i taea | ki te e wehea | ake ki te toru | te hihinga pōkākā paerewa, ara o DHA, DKG, me tetahi kotahi taonga "reductone"-rite, i rongoā D2O.
Ka hāngai | te uara pKa | o te hua hanga hopi (DKG), whakawakia | e te pH-kukū me te i-hihinga pōkākā, ki whakaaturia | ngā uara pKa | o ngā waikawameha "oxocarboxylic" (waikawameha "oxocarbonic").
Ka taea | te whanaketanga | o te CO2 | i roto i | te hihinga o pire | kia takina hoki | ki te DKG "decarboxylating". Heoi, he tonu rawa pūmau te DKG | i roto i | ngä nohanga | tiketike | i roto i | te otinga i te 37°C.
I te uiui (/korenga i) "qualitatively" | te tauhohe whāwehe | o DKG, | timata mai i ngā whaea-rongoā (/ rahui-rongoā, kararehe-rongoā) | o DKG, | hoki | i roto i | te whānuitanga pH | kūpapa me kawakore, | ki te kahore | me | te hihinga pōkākā, | tonu ki te "spectrophotometry", te "fluorescence" me hoki i te | hihinga te hāngai "paramagnetic" o irahiko (HPI).
Ka taea | e te rawa emerara-whero, (i) tipu i te uara pH tiketike | i rua, DHA me DKG, (i te mea) iu i te ritenga | ki awe irirangi, | e | whai pānga (/e pā ana) | ki | ngā tukanga "radicalic" utu.
I kitea | he tohu EPR, tohu tuwhena (/"radicals") R–O●.
Ko te raruraru, e awe | te whakaiti me te hāora | i tapepe (/"instabilities") | o DHA me DKG.
Na reira, te whakaiti | kore rawa | anake | i te kukū "equimolar" o NADH | te DHA | i roto i | te whānuitanga pH whaiaroaro | no te mea | o te "saponification" anō o DHA.
Ko te taua | ko te tika | ki ngä | te matū, kei roto ngā rōpū H–S, | hoki i kitea | he tikanga | tauhohe kitea, | rite ki te "saponification" o DHA.
Heoi, kï he āhua takawaenga, | e whai ana | i te tauhohenga whakaiti tūturu | o te DHA, | ki te hihinga pōkākā | e tauhohe | ki te rōpū H–S.
Mārama ngā rerekētanga | o hihinga pōkākā | i kitea | i te piti hāora tauhohe | i waenga i | pärönaki, | e te oreraa ranei e nehenehe | o "cyclization" o C(6)–O–C(3).
vorläufiges Bearbeitungsende; später mehr ...:
5 Whakarāpopototanga
I roto i tenei mahi, i tātarihia me te ōhikitanga me whakaitinga o te pūnaha retōh o te waikawa kāweikōaro3) me te waikawa kāweikōaro-hauwaitatango6) rite te paparetanga kawakore i waikawa kāweikōaro-hauwaitatango6) (DHA) ki DKG8) (DKG). Ki te awhina o ngā tawhā ropu kitea, o ngā hihinga o paerewa me tōkarikari (kitea) i ngā inenga pōkākā i roto i ngā matū, i ngā rōpū here o te H–O me C=O, i ite i te tautoko tino me te tukanga mō te mātakitaki i te hohenga ki te hihinga pōkākā rite te tikanga.
I roto i tenei hononga, i ako ngā raruraru9) o te takanga o te taua wāhanga hāparo-rua-waiwaro rua waihā i runga i 2,4-hāparo-rua rua pēwaro10) me waikawa (iho-)kāweikōaro.
I tua atu, ka tahuri te reira i roto i, i rerekē | te uara pakiaka tapawha | o te whakarea ngaro kura | momo wiri o totoro O=C, | e te hunga rite | ki te huringa taime dipole, | ratou auhia | i roto i | te whakauru | o ngā rōpū | here tata.
Ko te āhuatanga nei | o te hydration | o ngā rōpū keto i taea | ki te e whaia | ki te hihinga pōkākā | i roto i | te muingota māmā (hāparo-tahi pūwaro).
Ki te waikawameha "dehydroascorbic" | i roto i | otinga, he rangirua te tonu | te tikanga | no te mea | o te pānga | e rave rahi | o te mana tahi .
Heoi, hua ngā rerekētanga mārama | i waenganui i | te puka | tioata hoki | o te bis-DHA, me te puka "hydrated" o te DHA | i te rohe wiri totoro | o H–O me O=C.
E kore e rangirua te, ko angitu | mō te bis-DHA | i te "deuteration" | o te rōpū OH.
Hoki | i te tukanga | o te "saponification" | o te DHA, i whakaritea (/takoto) | "coherences" mahi | o te pāmahana | me te pH | me te pūngao whakahohe | o 79,3 kJ / mol.
Ki te awhina | o te tukatuka raraunga hiko (TRH), i taea | ki te e wehea | ake ki te toru | te hihinga pōkākā paerewa, ara o DHA, DKG, me tetahi kotahi taonga "reductone"-rite, i rongoā D2O.
Ka hāngai | te uara pKa | o te hua hanga hopi (DKG), whakawakia | e te pH-kukū me te i-hihinga pōkākā, ki whakaaturia | ngā uara pKa | o ngā waikawameha "oxocarboxylic" (waikawameha "oxocarbonic").
Ka taea | te whanaketanga | o te CO2 | i roto i | te hihinga o pire | kia takina hoki | ki te DKG "decarboxylating". Heoi, he tonu rawa pūmau te DKG | i roto i | ngä nohanga | tiketike | i roto i | te otinga i te 37°C.
I te uiui (/korenga i) "qualitatively" | te tauhohe whāwehe | o DKG, | timata mai i ngā whaea-rongoā (/ rahui-rongoā, kararehe-rongoā) | o DKG, | hoki | i roto i | te whānuitanga pH | kūpapa me kawakore, | ki te kahore | me | te hihinga pōkākā, | tonu ki te "spectrophotometry", te "fluorescence" me hoki i te | hihinga te hāngai "paramagnetic" o irahiko (HPI).
Ka taea | e te rawa emerara-whero, (i) tipu i te uara pH tiketike | i rua, DHA me DKG, (i te mea) iu i te ritenga | ki awe irirangi, | e | whai pānga (/e pā ana) | ki | ngā tukanga "radicalic" utu.
I kitea | he tohu EPR, tohu tuwhena (/"radicals") R–O●.
Ko te raruraru, e awe | te whakaiti me te hāora | i tapepe (/"instabilities") | o DHA me DKG.
Na reira, te whakaiti | kore rawa | anake | i te kukū "equimolar" o NADH | te DHA | i roto i | te whānuitanga pH whaiaroaro | no te mea | o te "saponification" anō o DHA.
Ko te taua | ko te tika | ki ngä | te matū, kei roto ngā rōpū H–S, | hoki i kitea | he tikanga | tauhohe kitea, | rite ki te "saponification" o DHA.
Heoi, kï he āhua takawaenga, | e whai ana | i te tauhohenga whakaiti tūturu | o te DHA, | ki te hihinga pōkākā | e tauhohe | ki te rōpū H–S.
Mārama ngā rerekētanga | o hihinga pōkākā | i kitea | i te piti hāora tauhohe | i waenga i | pärönaki, | e te oreraa ranei e nehenehe | o "cyclization" o C(6)–O–C(3).
| Nota: | Kupu taurite0) Māori: Maori'sche Synonyme: |
| 0) | kupu taurite
aronga ōrite |
| 1) | Tiamana
Tiamani Siamane |
| 2) | ketuketutanga
kimihanga rangahau hurahuratanga mātaitanga mātai ... tirohanga tūhuratanga akoranga |
| 3) | waikawa kāweikōaro5)
Huaora C |
| 4) | pārere ā-hihinga
wetenga ā-hihinga" |
| 5) | kāwei-kōaro
kāweikōaro kaweikoaro anti-scurvily (eng.) anti-scorbutic (eng.) ascorbic (eng.) |
| 6) | kāwei-kōaro-hauwai-ta-tango5)
kāweikōarohauwaitatango5) dehydroascorbic5) (eng.) |
| 7) | hāparo-rua rua
bi-keton (dts.) diketo- (dts.) |
| 8) | waikawa owaro (4S,5R)-4,5,6-waihā-toru 2,3-hāparo-rua rua
waikawa owaro (4S,5R)-4,5,6-waihā-toru 2,3-hāparorua rua waikawa owaro (4S,5R)-4,5,6-waihā-toru 2,3-hā rua waikawa owaro (4S,5R)-4,5,6-waihā-toru hāparo-rua,toru rua DKG Diketogulonic acid (eng.) waikawa kurono-hāparo-rua rua7) |
| 9) | mau fifi
raruraru |
| 10) | 2,4-hāparo-rua rua pēwaro
mewaro hāparo-rua-2-hāparo-rua pōwaro acetylacetone (eng.) |
| 11) | atiti
waikawa |
vorläufiges Bearbeitungsende; später mehr ...:
| Kupu matua, tino kupu (keywords): |
Detlef, Pagel, Giessen, 1992, DHA, DKG, NADH, pH, pKa, RPE, a: aċetun, aċid u, aċitil, aċtu, alkalin, vorläufiges Bearbeitungsende; später mehr ...: anelli, argomento, ascorbico, attivazione, bande, bis, butanal, calibratura, carbonici, cheto, coefficiente, concentrazioni, cristallino, decomposizione, déidro, deuterazione, dicheto, dipolo, elettronica, energia, enolica, estinzione, fisiologico, fluorescenza, formazione, fotometria, gruppo, gulonico, h: -, idratazione, idrolitica, inaugurale, infrarossa, instabilità, integrale, intermedio, interpretazione, iso, k: -, legami, madre, misurazioni, momento, neutrale, norma, ordine, ossidazione, osso, paramagnetica, parametri, pastiglie, prodotto, prova, radicale, raggio, reazione, rédox, reduttone, riassunto, riduzione, risonanza, saponificazione, settore, soluzione, spettro, spettroscopia, stabile, stato, tautomeria, temperatura, titolazione, u: -, valore, vibrazione, z: -, |
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